Solvent extraction of gallium (III) and aluminum (III) from alkaline solutions by 7-alkylated 8-hydroxyquinoline.
نویسندگان
چکیده
منابع مشابه
Utility of 1-octanol/octane mixed solvents for the solvent extraction of aluminum(III), gallium(III), and indium(III) with 8-quinolinol.
Using 1-octanol/octane mixed solvents, the extraction of aluminum(III), gallium(III) and indium(III) with 8-quinolinol was carried out at 25 degrees C. The formation constants of the respective metal(III) 8-quinolinolates in the aqueous phase and their partition constants between the mixed solvents and water were determined based on an analysis of the extraction equilibria. The relationship bet...
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Solid-phase extraction (SPE) of gallium(III) with hydrophobic 8-quinolinol derivatives (HQs)-impregnated resin from aqueous acidic and alkaline solutions has been investigated. The HQs used were 7-(4-ethyl-1-methyloctyl)-8-quinolinol (HEMOQ), 5-octyloxymethyl-8-quinolinol (HO(8)Q), 2-methyl-5-octyloxymethyl-8-quinolinol (HMO(8)Q), 5-dioctylaminomethyl-8-quinolinol (HN(8)Q), 7-bromo-5-octyloxyme...
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metal complexes, but is useful in the case of metal complexes with low extractability. This process has thus been applied to the separation of metals, which is difficult by conventional batch extraction.1 Extraction reagents (HR) are usually consumed in amounts several hundred times those of metals (M). Complexes to be extractable into an organic solvent {MRn·(HR)m} are not always obtained usin...
متن کاملExtraction of gallium(III) from hydrochloric acid solutions by trioctylammonium-based mixed ionic liquids.
The extractabilities of aluminium(III), gallium(III), and indium(III) from hydrochloric acid solutions were investigated using a mixture of two protic ionic liquids, trioctylammonium bis(trifluoromethanesulfonyl)amide ([TOAH][NTf(2)]) and trioctylammonium nitrate ([TOAH][NO(3)]). At a HCl concentration of 4 mol L(-1) or more, gallium(III) was nearly quantitatively extracted and the extractabil...
متن کاملComplex formation reactions of Scandium(III), Yttrium(III) and Lanthanum(III) complexes with 8-Hydroxyquinoline
This study aims to investigate the nature and types of complexes formed in aqueous solution between 8Hydroxyquinoline (HQ) and the ions of Sc, Y, and La. Potentiometric titration was used to follow the formation of complexes. The coordination compounds formed were studied through the determination of stability constants of these complexes in aqueous solution at 25,0 ± 0,1oC and ionic strength o...
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ژورنال
عنوان ژورنال: Journal of Japan Institute of Light Metals
سال: 1986
ISSN: 0451-5994
DOI: 10.2464/jilm.36.137